Outlook - Send As another Email Address on Windows Open a new email window Select the Options Tab on the Ribbon Select 'From' in the "Show Fields" group on the Ribbon This will reveal the "From" button in the message details section Select the "From" button in the Message details group, Then select "Other Email Address..." Select "From" from the first window Enter a Name to search Select the Account once you find it Select 'OK' from the prompt Select "Ok" from the 'Send from Other Email Address' windows The Email Address in the 'From' Section will now update.This will be the email address that the email will send from